Question: Why is hydrogen so isolated on Mendeleev's Periodic Table? While it is a special case in terms of how its properties fits the pattern, surely there are other elements like it?
It really is unique! It’s the smallest element, having only one proton and electron. The properties of elements are usually defined by how they interact; this in turn is governed by how ‘full’ their outermost shell of electrons is.
Electrons in atoms are arranged in concentric ‘shells’ of varying size; the smallest shell can hold a max of 2 electrons, the second holds a max of 8 and so on. If an element has a full outer shell it doesn’t react very much, these are called the noble gases. If it has only 1 electron in the outer shell it reacts in certain ways, and if it has 1 less than the the max number for its outer shell it reacts in different ways.
Now because hydrogen’s outer shell can only hold 2 electrons and it already has 1; it has 1 more than the minimum and 1 less than the maximum; meaning it has properties of both groups!
In Mendeleev’s original periodic table, hydrogen was placed in a row with silver, copper and mercury. However, I’m not very knowledgeable of the history of the periodic table so I don’t know why! But Ed has given a very good explanation of how the periodic table today is organised!
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